SELECT 
  category_to_id 
FROM 
  cscart_ble_category_redirects 
WHERE 
  category_from_url = '/finish-gallery/natural-metals/940-painted-aged-copper/'

Query time 0.00025

JSON explain

{
  "query_block": {
    "select_id": 1,
    "table": {
      "table_name": "cscart_ble_category_redirects",
      "access_type": "ALL",
      "rows": 81,
      "filtered": 100,
      "attached_condition": "cscart_ble_category_redirects.category_from_url = '/finish-gallery/natural-metals/940-painted-aged-copper/'"
    }
  }
}